Hunting powders, smoky and smokeless, composition, properties, application features, positive and negative qualities. Smokeless gunpowder: history of invention, composition, application. Hunting smokeless powder "Falcon" Who invented smokeless

Smokeless powder(English) Smokeless powder) or nitro powder(English) nitro powder) - a group name for propellant explosives used in firearms and artillery, in solid rocket engines, which upon combustion do not produce solid particles (smoke), but only gaseous combustion products, in contrast to black powder.

Types of smokeless powder include Cordite (English) corde- wire) - smoke-free nit-ro-gly-tse-ri-no-pi-rock-si-li-new powder in the form of pro-vo-lo-ki.">cordite, Ballistitis (or ball-li-stitis in ro-ha) is the general name for one of the types of go-mo-gene solid fuels (without- smoky on-ro-khov), the main-new-my-com-on-nen-ta-mi of which-ly-y-y-ya nit-ra-you are whole-lov-lo-zy and nit-ro-ether solutions, for example, nit-ro-gly-cerin. In the za-ru-be-no-li-te-ra-tu-re they are called two-os-nov-ny-mi (English. double base). Ball-li-sti-tom (English) ballistite) also called the smoke-free powder, behind the ten-to-van Al-fre-house of No-bel-lem.
When iz-go-to-le-niy ball-li-stit-no-go po-ro-ha nit-ro-tsel-lu-lo-za-la-ti-ni-zi-ru-et-sya tech-no-lo-gi-che-additions, improving me-ha-ni- che-skie and hi-mi-che-skie properties of go-to-go-ro-ha. In za-vi-si-mo-sti from hi-mi-che-sko-sta-va and co-from-no-she-niya of com-nen-tov there are different con- -kret-nye brands po-ro-khov. So, in the ex-per-ri-mental research of the state of ball-li-stity of the most shi-ro -some use po-rokh N, in which, by weight, 56.44% of the amount of chlorine is contained with 11.7-12.2% nitrogen, 27.72% nitrous ro-gli-tse-ri-na, 10.89% di-nit-ro-to-lu-o-la, 2.97% tsen-tra-li-ta, 0.99% wa-ze-li- on and 0.99% water.">ballistitis
and, traditionally, white powder Poudre B). They are classified into single-base, double-base and tri-base.

Smokeless powder

Smokeless powder is made from nitrocellulose ( monobasic), usually with the addition of up to fifty percent nitroglycerin ( dibasic), and sometimes nitroglycerin in combination with nitroguanidine ( tribasic). The final product is granulated into spherical particles or pressed into cylinders or flakes using solvents such as ether. Also, additional components of smokeless powder can be stabilizers and ballistic modifiers. Double-base propellants are commonly used in the manufacture of shotgun and machine gun cartridges, while tri-base propellants are more widely used in artillery.

The reason for the smokelessness of these powders is that the oxidation products of their ingredients are mainly gaseous, compared to black powder, which releases up to 55% of solids during combustion (potassium carbonate, potassium sulfate, etc.).

Smokeless powder burns only on the surface of granules, flakes or cylinders - for short, granules. Larger granules burn more slowly and the rate of their combustion is also controlled by a special coating that interferes with combustion, the main function of which is to regulate a more or less constant pressure on the rotating bullet or projectile, which has not yet left the gun barrel, which allows them to reach maximum speed.

The largest granules in cannon powder. They are a cylinder, reaching the size of a finger, in which seven holes are made (one along the axis of symmetry, and the remaining six are located in a circle of the central cross section). These holes stabilize the combustion process due to the fact that while the outer surface, burning, reduces the external combustion area, the inner surface also burns, increasing the internal combustion area. From the inside, combustion in the pellet occurs faster, thus allowing the pressure in the barrel to be maintained constant, while the free space in it increases due to the forward movement of the bullet/projectile.

Fast-burning pistol powders are made to maximize the surface area of ​​their granules, like flakes or flat disks.

Gunpowder is dried mainly in a vacuum. When dried, the solvents condense and can be reused in the manufacturing process. The granules are also coated with graphite to prevent them from igniting from sparks of static electricity.

Smokeless gunpowder enabled the development of modern semi-automatic and automatic weapons. Black powder left a thin and viscous coating on gun barrels that was hygroscopic and corrosive, while smokeless powder did not have this negative property, allowing automatic reloading of weapons using many moving parts.

Single- and dual-base smokeless powders now make up the bulk of explosives used in small arms. They are so generally accepted that most uses of the word "powder" refer specifically to smokeless powder, particularly when referring to handguns.

White powder

In 1884, Paul Viel invented a smokeless gunpowder called Poudre B, which was based on gelatinized nitrocellulose (68% trinitrocellulose insoluble in diethyl ether mixed with 30% dinitrocellulose dissolved in ether with the addition of 2% paraffin), with the further formation of gunpowder elements and subsequent drying of the gunpowder grains.

The final explosive, which today is called nitrocellulose, contains a slightly smaller amount of nitrogen than pyroxylin, so it is more easily gelled by the alcohol-ether mixture. The great advantage of this gunpowder was that, unlike pyroxylin, it burns in layers, which made its ballistic properties predictable.

Viel gunpowder revolutionized the world of small arms for several reasons:

  • There was virtually no smoke anymore, whereas previously, after several shots using black powder, the soldier's field of vision was greatly reduced due to clouds of smoke, which could only be corrected by a strong wind. In addition, the shooter's position was not indicated by a puff of smoke from the rifle.
  • Poudre B gave a higher bullet velocity, which meant a straighter trajectory, which increased accuracy and range; The firing range reached 1000 meters.
  • Since Poudre B was three times more powerful than black powder, much less of it was needed. Ammunition was made lighter, allowing troops to carry more ammunition for the same weight.
  • The cartridges worked even when wet. Ammunition based on black powder had to be stored in a dry place, so they were always carried in closed packages that prevented moisture from entering.

From a technological point of view, to obtain gunpowder, cellulose, nitric and sulfuric acid (as opposed to charcoal, saltpeter and sulfur in black powder) were now needed. Wood could be used as a source of cellulose; cotton could be better and easier. By that time, the production of sulfuric acid had been fully developed. Nitric acid was initially obtained from the same nitrates - saltpeter, the main supplier of which was Chile (in the form of NaNO 3). During the First World War, German engineers developed a very effective process for producing nitric acid from atmospheric nitrogen. Initially, air (20% O 2 and 80% N 2) was passed through hot coal, which burned to CO. Carbon monoxide, when interacting with water vapor, gave hydrogen CO + H 2 O = CO 2 + H 2, carbon dioxide was removed, and the result was a mixture of nitrogen and hydrogen, from which it was easy to obtain ammonia 3H 2 + N 2 = 2NH 3. Ammonia was converted by oxidation into nitrogen oxides and nitric acid. That is, now to obtain nitric acid, only coal was needed (as paradoxical as it sounds), and there could be no problems with the rest of the raw materials - air and water. Cotton wool, or wood, sulfuric acid and coal - all that turned out to be needed for industrial war.

Viel's gunpowder was used in the Lebel rifle, which was immediately adopted by the French army to take full advantage of the new gunpowder over black. Other European countries hastened to follow the example of the French and also switched to analogues of the Poudre B. The first were Germany and Austria, which followed it, which introduced new weapons in 1888.

Ballistite and cordite

Around the same time as Viel in 1887 in Great Britain Alfred Nobel developed ballistitis, one of the first nitroglycerin smokeless powders, consisting of equal parts gunpowder and nitroglycerin, and received a British patent for it.

Ballistite has been modified Frederic Abel And James Dewar into a new composition called cordite. It also consists of nitroglycerin and gunpowder, but uses the most nitrated variety of gunpowder, insoluble in mixtures of ether and alcohol, while Nobel used soluble forms. Cordite became the main type of smokeless explosive in service with the British Army during the 20th century.

Cordite was the subject of lawsuits between Nobel and the British government in 1894 and 1895. Nobel believed that his patent for ballistite also included cordite; in practice, it was impossible to prepare one of the forms in its pure form, without an admixture of the second. The court ruled against Nobel.

In 1889, a British patent for a similar composition was also received by gunsmith Hiram Maxim, and in 1890 his brother Hudson Maxim patented this composition in the USA.


These new explosives were more stable and safer to handle than white powder, and, importantly, more powerful.

Contrary to popular belief, gunpowder is not an explosive. Gunpowder is fuel. It can explode if handled incorrectly, it can explode if it is “requested”, it can explode without outside intervention if the processes of destruction and decay have gone too far. Some components of gunpowder are also explosive. Still, gunpowder is fuel. It was invented for the sake of combustion, not explosion. But gunpowder is a special fuel. Unlike most substances, it does not require air to burn. Gunpowder of any composition and brand burns “due to internal resources” - oxygen, which is part of the powder composition.

Powder making- one of the oldest chemical industries existing on our planet. Several centuries before our era, the Chinese discovered the ability of saltpeter to support the combustion of various substances and began to select different flammable compositions with it. Through trial and error, they came up with the classic recipe for black gunpowder: coal, saltpeter and sulfur in equal proportions. The composition and recipe for making gunpowder were described by the Chinese scientist Sun-Simyao back in 600 AD. e. And half a millennium later, the first firearms were made in China. The hollow bamboo trunk became the barrel of the first gun, and the propellant, naturally, was black powder.

Later this invention spread throughout the world. In medieval Europe, according to most historians, gunpowder was reinvented. Even the name of this discoverer, the Freiburg monk Berthold Schwartz, “Black Berthold,” is indicated. But information about him is contradictory. According to some sources (not very reliable), the date of the invention of gunpowder in Europe is 1259, according to others - almost a hundred years later, and according to others, Berthold Schwartz cannot be considered the inventor of gunpowder at all, because even earlier, before Schwartz, Roger Bacon developed the formula explosive, which included saltpeter and sulfur. Perhaps this was the first European gunpowder.

Muscovite Rus' became acquainted with gunpowder in the 14th century - definitely before 1382, because it is known from the chronicles: in this year Muscovites defended their city from the army of the Tatar Khan Tokhtamysh with the help of firearms...

Black powder has a long history. They loaded all squeaks and mortars, all muskets and flintlocks, and later, until the last years of the 19th century, even more advanced means of shooting.

Many famous scientists researched and improved black powder. Suffice it to recall Lomonosov, who established a rational ratio of the components of the powder mixture. One can also recall Claude Louis Berthollet’s unsuccessful attempt to replace the scarce saltpeter in gunpowder with potassium chlorate, or potassium chlorate. Numerous explosions got in the way of this replacement - Berthollet's salt turned out to be too active an oxidizing agent...

One of the most notable milestones in the history of gunpowder production should be considered 1832, when the French chemist A. Bracono first obtained nitrocellulose, or pyroxylin.

Nitrofiber is an ester of cellulose and nitric acid. The cellulose molecule contains a large number of hydroxyl groups, which react with nitric acid.

Depending on how many OH groups are esterified, i.e., reacted with nitric acid, nitrocellulose is obtained containing from 9 to 14% nitrogen, and the properties of nitrocellulose, its hygroscopicity and solubility in different solvents depend on this. Low-nitrated cellulose - colloxylin - dissolves even in water, and highly nitrated cellulose, called pyroxylin, dissolves only in a mixture of ethanol and ether.

The properties of pyroxylin have been studied by many scientists. In particular, by the end of 1848, Russian engineers G. I. Hess and A. A. Fadeev established that pyroxylin was several times more powerful than black gunpowder. They tried to use pyroxylin for shooting, but were unsuccessful. Loose porous nitrocellulose was heterogeneous and burned at a far from constant rate, and often ignited during pressing. Only in 1884 did the French chemist J. Viel manage to create a monolithic horn-like substance based on pyroxylin. This was the first smokeless powder. Viel used the ability of pyroxylin to swell in a mixture of ether and alcohol to produce gunpowder. This produced a jelly-like mass that could be pressed and made into ribbons or plates, which were then dried. Most of the solvent evaporated, and a smaller part remained in the pyroxylin, continuing to play the role of a plasticizer. Pyroxylin powder consists almost entirely, 80-95%, of this mass. Unlike unplasticized pyroxylin, pyroxylin powder burns strictly in layers at a constant speed. Strictly natural combustion is a mandatory property of any of the gunpowders. Pyroxylin powder is still used for small arms.

Soon another one appeared smokeless powder- nitroglycerin, also known as ballistitis. It was also based on nitrocellulose, although its amount in the recipe was reduced to 56-57%. The plasticizer here is the liquid explosive trinitroglycerin (a separate essay about it). This gunpowder is very powerful and is still used in artillery and rocket forces.

The third type of smokeless gunpowder was cordite, invented in 1889 in England - a cross between ballistite and pyroxylin gunpowder; it has almost fallen into disuse.

In the early nineties, Russia developed its own recipe for smokeless powder. This is Mendeleev's pyrocollodion powder.

Mendeleev devoted a lot of effort and attention to gunpowder, as a field of chemical knowledge, in the years 1890-1894. He traveled to France and England, became acquainted with the production of gunpowder; he met with Viel, Abel, Dewar, Arnoux, Sarro and other leading gunpowder scientists of the time. He found a way to obtain soluble nitrocellulose - pyrocollodium, and in his research he proceeded from a very specific and chemically strictly substantiated idea: the desired substance, when burned, should release a maximum of gaseous products per unit mass. This means that there must be enough oxygen in its composition to convert all carbon into gaseous oxide, and hydrogen into water.

Already in 1892, the first experimental firing with pyrocollodion gunpowder was carried out. The shooting was successful. A year later, for the first time in Russia, smokeless powder was fired from a 12-inch gun, and naval artillery inspector Admiral S. O. Makarov congratulated Mendeleev on his brilliant success.

Mendeleev “considered his work completed from the time when pyrocollodium gunpowder withstood the experiments of the sea test site in guns of all calibers.” But the great scientist’s services to gunpowder production and military affairs are not limited to this. He made a very important improvement in the technology of gunpowder production, proposing, instead of drying nitrocellulose, dehydrating it with alcohol. This improvement not only made gunpowder production safer, but also improved the quality of nitrocellulose: alcohol washed out less stable products from it...

Here we touched upon a very important issue - the issue of temporary and physico-chemical stability of smokeless powders. Even at normal temperatures, nitrocellulose spontaneously decomposes. As the temperature increases, the rate of decomposition also increases. Almost all contaminants, and in particular acid residues that are not washed out of nitrocellulose after nitration, greatly accelerate decomposition, and this process is self-accelerating... Under unfavorable conditions, this increasing decomposition can lead to self-ignition of gunpowder and even an explosion.

To prevent this from happening, to increase the resistance of smokeless powders, stabilizers are introduced into their composition - substances that bind decomposition products and thereby prevent a chain reaction of decomposition from developing. Such stabilizer substances are some carbamide (urea) derivatives, the so-called centrolites, and diphenylamine.

Other additives for various purposes are also added to the composition of gunpowders. In laboratories, chemists, using the most precise analytical balances, are constantly improving the composition of gunpowder. For example, to reduce the flame when fired, potassium sulfate is added to the gunpowder. Substances that reduce the heat of combustion, such as dinitrotoluene, are added to artillery powders. They do this to reduce barrel wear or fire, as artillerymen say. There are also purely technological additives. Grained gunpowder, for example, is coated with a thin layer of graphite so that it does not become electrified when stirred. In a word, smokeless powder is a multi-component strictly balanced system. When drawing up this balance, everything is taken into account: ballistics, technology, safety precautions, and economics.

Today, gunpowder is not only artillery fuel, but also solid rocket fuel (SRF).

Solid fuel is inferior to liquid fuel in some important indicators, primarily in specific impulse. Therefore, in particular, space rockets use mainly liquid fuel. But the TRT also has advantages, the main ones being the simplicity of the design of a solid-fuel jet engine and the constant combat readiness of solid-fuel missiles.

Smokeless powders are used to make large powder balls for rockets. Gunpowders containing nitroglycerin produce more heat when burned. Their specific impulse is higher than that of pyroxylin powders. It is also important that today ballistic gunpowder is cheaper than pyroxylin powder.

The newest book of facts. Volume 3 [Physics, chemistry and technology. History and archaeology. Miscellaneous] Kondrashov Anatoly Pavlovich

How was smokeless gunpowder invented?

How was smokeless gunpowder invented?

In 1845, German chemist Christian Friedrich Schönbein (1799–1868) conducted an experiment in the kitchen of his home using a mixture of nitric and sulfuric acids. His wife strictly forbade him to bring his flasks into the kitchen, so he hurried to finish the experiment in her absence - and spilled some of the caustic mixture on the kitchen table. Fearing a scandal, he grabbed the first rag he could get his hands on (it turned out to be a cotton kitchen apron), wiped the puddle off the table, and then hung the apron in front of the fireplace. Once dry, the apron exploded. Schönbein immediately realized what he had got. The name he gave to the new substance literally translates from German as “shooting cotton,” but chemists now call it nitrocellulose. Schönbein sold the recipe for the production of a new explosive to several governments at once. At that time, the artillery used black powder, the soot from which stained the guns so much that they had to be cleaned between shots, and after the first salvos such a curtain of smoke rose that they had to fight almost blindly. The military was enthusiastic about the explosive, which produced significantly less smoke and was also more powerful than black powder. They began to build factories for the production of nitrocellulose, but they exploded very quickly. Nitrocellulose was too impatient to wait for battles, so its use had to be abandoned in the early 1860s. Later, however, they came up with a way to purify nitrocellulose from impurities that caused spontaneous explosions, and nitrocellulose became safe to use. And in 1884, the first smokeless gunpowder was invented - pyroxylin. It was made from nitrocellulose with a nitrogen content of over 12 percent (pyroxylin) with the addition of substances that gave the gunpowder special properties.

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When was the crossbow invented? One of the oldest types of weapons is the bow. A crossbow is the same as a bow, only its string is pulled mechanically. The first crossbow was invented around 1050 in France. An arrow fired from a crossbow could fly 305 meters or more. Crossbow -

Black powder or black powder is a mixture of three substances: sulfur, coal and potassium nitrate in a ratio of 2:3:15. The mixture was initially obtained by crushing it in a special container.

Was gunpowder invented by the Chinese?

If you try to find the exact date of the invention of gunpowder, you are unlikely to succeed. Some sources say that gunpowder was known to the ancient Indians as early as one and a half thousand years BC, others say that gunpowder was known to the Chinese at the beginning of the first century AD. Many historians agree that the Chinese were the first to invent gunpowder. True, they did not use it for military purposes. Saltpeter was used in medicine. It was mixed with other substances (for example, honey) and set on fire, producing “healing” smoke. The Chinese also used gunpowder as entertainment during festivals. The well-known fireworks first appeared in China, and then spread to Europe. The Chinese filled a piece of bamboo with gunpowder and set it on fire, pointing the stick at the sky. There are also references to gunpowder as a weapon - these were bombs “pi li huo qiu” (translated from Chinese as “fireball with the sound of thunder”). They were put into catapults and thrown at the enemy.

But the Chinese and Arabs were never able to figure out how to use the power of gas to launch projectiles. It was the Europeans who did this first. Everywhere you can find one legend that Berthold Schwartz accidentally ground a mixture of gunpowder in a mortar, and a random spark got there and caused an explosion in the monk’s cell. True, there is no reliable information about Schwartz, but still, it was the monks who were the first to accurately describe gunpowder, namely the great inventor of the Middle Ages, Roger Bacon. He would definitely write down the recipe for gunpowder, but would not dare to show it further than the monastic order, because it was believed that such dangerous things should be hidden from the eyes of uneducated people.

However, the secret of gunpowder was soon revealed and used as a weapon for the first time.

Gunpowder as a weapon

August 26, 1346. After months of fighting for the French crown, the English king Edward III and his weary army reached the village of Crecy in northern France. For a millennium, horsemen dominated the battlefields. There were few Englishmen, but they were inspired by faith in their own weapons - longbows. Having fought for many years with the Scots and Welsh, Edward appreciated the quality of this powerful weapon. At dawn, the English warriors began to strengthen their position at Crecy, the pits were intended to become traps for the French cavalry. At the approaches to the battle formations, stakes were driven into the ground that could pierce a horse. However, first of all, the British pinned their hopes on their main trump card - the longbow. As tall as a man, it was made of yew; to pull the bowstring it was necessary to apply a force of 45 kilograms, and the arrows hit the enemy up to 200 meters. It was more difficult to string a bow than a crossbow, but it was much faster to shoot. While the English archers were preparing to meet the enemy, Edward arrived on the battlefield along with the knights, but now the English cavalry had to fight on foot. Edward ordered the knights to dismount and take up position among the archers, forming a wedge-shaped formation called the furrow. “England and St. George! England and St. George! - the soldiers chanted.

The French had no doubt about victory, because their army was three times larger than the British. They countered the English bows with powerful crossbows. The French king Philip brought with him 6 thousand Genoese mercenaries. Armed with crossbows, they descended the hill and moved towards the British battle formations.

Modern historian Geoffrey Baker describes the battle this way:

The French rushed towards the British first. The crossbowmen walked towards them to the sound of trumpets, kettledrums and a piercing howl that filled the area with a thunderous cry.

However, the crossbowmen's arrows did not reach the British. The British stood out of reach of the Genoese crossbows. While the arrows of long English bows were quite enough to reach the crossbowmen. The archers took a step forward and began to shoot arrows with such speed that they fell like snow. Throwing down their weapons, the Genoese fled. This sight outraged the French king so much that he ordered his knights to attack the enemy on horseback. The knights rushed forward through the disorganized ranks of retreating crossbowmen. The ground on the battlefield was wet after recent rain. Soon the French battle formations turned into a shapeless and mud-stained heap of people in heavy equipment and horses, showered with a hail of arrows from the British. The French were in confusion, and only a few knights, seized by a furious impulse, managed to get close to the British. Here the axes, spears and swords of the British were already waiting for them. A lot of French died without receiving a single wound; they were simply crushed in the crowd. After 16 fruitless attacks, the French retreated, suffering a crushing defeat. The British maintained their battle formation until the next morning.

At dawn, Edward's ambassadors discovered 542 bodies of French nobles and knights, as well as 20 thousand dead soldiers and horses. The British lost 2 knights and 18 infantry. The British victory at Crecy stunned Europe. Their tactics, which relied on the power of longbows, came as a complete surprise to the Europeans. A new era was dawning for the infantrymen, the cavalrymen were destined to appear on the battlefields for several more centuries, but they would no longer decide the outcome of the battle. The era of knightly cavalry came to an end, but on the battlefield at Crecy the sound of not only the English was heard, Edward placed several bombards in position. These were small, primitive cannons that fired stones. Bombards were inaccurate weapons and mainly only frightened the French horses with their roar. However, it was their cannonade that heralded the beginning of a revolution that was to change the world forever, as well as the way of warfare - the appearance of gunpowder.

Subsequently, gunpowder began to be used more and more often in military affairs and returned to the east as a new technology. For example, the Ottoman Sultan Mehmed II “The Conqueror” was able to use the new type of weapon extremely successfully. He used technology suggested to him by Urban, a Hungarian engineer.

Turkish cannon made using the same technology

Mehmed developed a plan for the siege of the city. He installed a cannon opposite the main gate of the city. On April 12, 1453, she finally “spoke.” The powerful walls that had protected Christianity for centuries collapsed within weeks. This super-cannon of Mehmed managed to change the course of history, but such a weapon turned out to be not very convenient for waging a siege. It required 60 oxen and 200 men to transport it; it took at least an hour to load the weapon into position. The recoil was so great that a new shot could only be fired 3 hours after the previous one.

Further development of this technology in the military leads to the emergence of a huge number of rifles, cannons, mortars and other weapons. But this type of gunpowder was not yet perfect enough for military purposes for many reasons. One of the main reasons is the release of a large amount of smoke, which during shooting indicated the shooter’s position, but at the same time interfered with aimed fire. Secondly, black powder is extremely sensitive to fire. Many cases are described when barrels of gunpowder exploded right in warehouses due to all sorts of little things (a small spark or just a blow from a metal object). All this and much more made me think about how to make gunpowder smokeless.

How gunpowder was invented in Russia

At first, black smoky gunpowder was used for shooting in the form of pulpy powder-like gunpowder, and the word “gunpowder” or “dust” itself means dust. It was difficult to use such powder pulp because it stuck to the walls of the guns. As a result of thinking about this problem, it was decided to make gunpowder in the form of lumps, which made it easier to load the guns, and thus obtain a significantly larger volume of gas when ignited. Somewhere in the mid-15th century we began to use green gunpowder. It could be obtained by rolling gunpowder pulp into dough along with alcohol and other impurities, then passing the dough through a special sieve. The development of domestic gunpowder production received a significant boost during the reign of Ivan the Terrible, as well as Peter I. Under Peter the Great, three gunpowder factories were built at once: St. Petersburg, Sestroretsk, and Okhtinsky.

The study of gunpowder in Russia was carried out by Lomonosov, who made theoretical calculations, as well as a number of experiments on black gunpowder. Later, his findings were used by French scientists, who obtained the most successful composition of the mixture, which is described at the beginning of the article: 75% potassium nitrate, 10% sulfur and 15% coal.

At the beginning of the 19th century, Russian gunpowder began to be considered one of the highest quality in the world, but, as is known, black gunpowder had significant disadvantages, such as clogging of the gun barrel as a result of the adhesion of gunpowder particles, as well as a huge amount of smoke when firing. Another significant drawback was the formation of sulfur compounds, even sulfurous acid, which corroded the metal parts of the weapon.

By the end of the 19th century, white gunpowder, later called smokeless, was invented, which was based on nitrocellulose. This gunpowder burned in layers, which improved the ballistic properties of the projectiles. White gunpowder produced a much smaller amount of smoke when burned, which made a big breakthrough in the development of artillery.

In 1884, pyroxylin gunpowder was invented in France, which proved to be more powerful than black powder, but more unpredictable, so it was used only in small guns.

In 1887, Alfred Nobel invents ballistic gunpowder. In England, in 1889, cordite gunpowder was created, based on Nobel's ballistic gunpowder. The new substances were more powerful, but also more stable than white powder or gunpowder.

In 1891, Dmitry Ivanovich Mendeleev created pyro-collodion gunpowder and a year later began testing it for military purposes. As a result, it is adopted into service. D.I. Mendeleev extremely scrupulously compares his invention with other types of gunpowder in his works and notes its advantages: stability of composition, homogeneity, absence of “detonation traces”.

It was in the USSR that the first multiple launch rocket systems were created. We successfully used ballistic gunpowder for rocket system charges, and in the late 1940s we created mixed types of gunpowder that were used in rocket engines.

Nothing stands still, because more and more new types of weapons are being created, and no one is in a hurry to give up war, which means gunpowder will be in demand and work for a long time...

You can also watch a documentary about gunpowder:

Man has made many discoveries that were of great importance in one area or another of life. However, very few of these discoveries actually affected the course of history.

Gunpowder and its invention are precisely from this list of discoveries that contributed to the development of many areas of humanity.

Story

Background to the appearance of gunpowder

Scientists have debated for a long time about the time of its creation. Some argued that it was invented in Asian countries, while others, on the contrary, disagree and prove the opposite, that gunpowder was invented in Europe, and from there it came to Asia.

Everyone agrees that China is the birthplace of gunpowder.

The existing manuscripts speak of noisy holidays that were held in the Middle Kingdom with very loud explosions that were not familiar to Europeans. Of course, it was not gunpowder, but bamboo seeds, which burst with loud noise when heated. Such explosions made Tibetan monks think about the practical application of such things.

History of invention

Now it is no longer possible to determine with an accuracy of one year the time of the invention of gunpowder by the Chinese, however, according to manuscripts that have survived to this day, there is an opinion that in the middle of the 6th century, the inhabitants of the Celestial Empire also knew the composition of substances with the help of which fire with a bright flame could be obtained. The Taoist monks advanced the furthest towards the invention of gunpowder, who eventually invented gunpowder.

Thanks to the found work of monks, which was dated back to the 9th century, which contains lists of all certain “elixirs” and how to use them.

Much attention was paid to the text, which indicated the prepared composition, which unexpectedly ignited right after production and caused burns to the monks.

If the fire was not put out immediately, the alchemist’s house would burn to the ground.

Thanks to such information, discussions about the place and time of the invention of gunpowder were ended. Well, I must say that after the invention of gunpowder, it only burned, but did not explode.

The first composition of gunpowder

The composition of gunpowder required an exact ratio of all components. It took the monks another year to determine all the shares and components. As a result, a mixture was obtained that received the name “fire potion.” The potion contained molecules of coal, sulfur and saltpeter. There is very little saltpeter in nature, with the exception of the territories of China, where saltpeter can be found directly on the surface of the earth in a layer of several centimeters.

Gunpowder components:

Peaceful uses of gunpowder in China

When gunpowder was first invented, it was mainly used in the form of various sound effects or for colorful “fireworks” during entertainment events. However, local sages understood that the combat use of gunpowder was also possible.

China in those distant times was constantly at war with the nomads around it, and the invention of gunpowder was in the hands of military commanders.

Gunpowder: First military use by the Chinese

There are manuscripts by Chinese monks that claim the use of a “fire potion” for military purposes. The Chinese military surrounded the nomads and lured them into a mountainous area, where gunpowder charges were pre-installed and set on fire after the enemy’s campaign.

Strong explosions paralyzed the nomads, who fled in shame.

Having understood what gunpowder is and realizing its capabilities, the emperors of China supported the production of weapons using a fiery mixture, including catapults, powder balls, and various projectiles. Thanks to the use of gunpowder, the troops of the Chinese commanders did not know defeat and put the enemy to flight everywhere.


Gunpowder leaves China: Arabs and Mongols begin to make gunpowder

According to information received, around the 13th century, information about the composition and proportions for the manufacture of gunpowder was obtained by the Arabs; there is no exact information about how this was done. According to one legend, the Arabs massacred all the monks of the monastery and received a treatise. In the same century, the Arabs were able to build a cannon that could fire gunpowder shells.

"Greek Fire": Byzantine Gunpowder


Further information from the Arabs about gunpowder and its composition in Byzantium. By slightly changing the composition qualitatively and quantitatively, a recipe was obtained, which was called “Greek fire”. The first tests of this mixture were not long in coming.

During the defense of the city, cannons loaded with Greek fire were used. As a result, all the ships were destroyed by fire. Accurate information about the composition of “Greek fire” has not reached our times, but presumably it was used - sulfur, oil, saltpeter, resin and oils.

Gunpowder in Europe: who invented it?

For a long time, Roger Bacon was considered the culprit behind the appearance of gunpowder in Europe. In the mid-thirteenth century, he became the first European to describe in a book all the recipes for making gunpowder. But the book was encrypted, and it was not possible to use it.


If you want to know who invented gunpowder in Europe, then the answer to your question is the story of Berthold Schwartz. He was a monk and practiced alchemy for the benefit of his Franciscan Order. At the beginning of the fourteenth century he worked to determine the proportions of the substance from coal, sulfur and saltpeter. After much experimentation, he managed to grind the necessary components in a mortar in a proportion sufficient to cause an explosion.

The blast wave almost sent the monk to the next world.

The invention marked the beginning of the era of firearms.

The first model of the “shooting mortar” was developed by the same Schwartz, for which he was sent to prison in order to not disclose the secret. But the monk was kidnapped and secretly transported to Germany, where he continued his experiments in improving firearms.

How the inquisitive monk ended his life is still unknown. According to one version, he was blown up on a barrel of gunpowder; according to another, he died safely at a very old age. Be that as it may, gunpowder gave the Europeans great opportunities, which they did not fail to take advantage of.

The appearance of gunpowder in Rus'

There is no exact answer about the origin of gunpowder in Rus'. There are many stories, but the most plausible is considered to be that the composition of the gunpowder was provided by the Byzantines. For the first time, gunpowder was used in a firearm when defending Moscow from a raid by the troops of the Golden Horde. Such a gun did not incapacitate the enemy’s manpower, but made it possible to frighten horses and sow panic in the ranks of the Golden Horde.


Smokeless powder recipe: who invented it?


Approaching more modern centuries, let's say that the 19th century is a time of improvement of gunpowder. One of the interesting improvements is the invention of pyroxylin powder, which has a solid structure, by the Frenchman Viel. Its first use was appreciated by representatives of the defense department.

The point is that the gunpowder burned without smoke, leaving no traces.

A little later, inventor Alfred Nobel announced the possibility of using nitroglycerin gunpowder in the production of projectiles. After these inventions, gunpowder was only improved and its characteristics improved.

Types of gunpowder

The following types of gunpowder are used in the classification:

  • mixed(the so-called black powder (black powder));
  • nitrocellulose(respectively, smokeless).

It may be a discovery for many, but solid rocket fuel used in spacecraft and rocket engines is nothing more than the most powerful gunpowder. Nitrocellulose powders consist of nitrocellulose and a plasticizer. In addition to these parts, various additives are mixed into the mixture.

The storage conditions of gunpowder are of great importance. If the gunpowder is found beyond the possible storage period or the technological storage conditions are not met, irreversible chemical decomposition and deterioration of its properties are possible. Therefore, storage is of great importance in the life of gunpowder, otherwise an explosion may occur.

Black powder

Black powder is produced on the territory of the Russian Federation in accordance with the requirements of GOST-1028-79.

Nowadays, the production of smoky or black powder is regulated and complies with regulatory requirements and rules.

The types of gunpowder are divided into:

  • grainy;
  • powder powder.

Black powder consists of potassium nitrate, sulfur and charcoal.

  • potassium nitrate oxidizes, allowing to burn at a rapid rate.
  • charcoal is a fuel (which is oxidized by potassium nitrate).
  • sulfur- a component that is necessary to ensure ignition. The requirements for the proportions of black powder grades are different in different countries, but the differences are not large.

The shape of granular grades of gunpowder after production resembles grain. Production consists of five stages:

  1. Grind to powder;
  2. Mixing;
  3. Pressed onto discs;
  4. Grain crushing occurs;
  5. The grains are polished.

The best grades of gunpowder burn better if all components are completely crushed and thoroughly mixed, even the output shape of the granules is important. The combustion efficiency of black powder is largely related to the fineness of grinding of the components, the completeness of mixing and the shape of the finished grains.

Types of black powders (% composition KNO 3, S, C.):

  • corded (for fire cords) (77%, 12%, 11%);
  • rifle (for igniters for charges of nitrocellulose powders and mixed solid fuels, as well as for expelling charges in incendiary and illuminating shells);
  • coarse-grained (for igniters);
  • slow-burning (for intensifiers and moderators in tubes and fuses);
  • mine (for blasting) (75%, 10%, 15%);
  • hunting (76%, 9%, 15%);
  • sports.

When handling black powder, you must take precautions and keep the gunpowder away from an open source of fire, as it ignites easily; a flash at a temperature of 290-300 °C is sufficient for this.

There are high requirements for packaging. It must be sealed and black powder must be stored separately from the rest. Very picky about moisture content. If the moisture content is more than 2.2%, this powder is very difficult to ignite.

Before the beginning of the 20th century, black powder was invented for use in firing weapons and in various throwing grenades. Now used in the production of fireworks.

Varieties of gunpowder

Aluminum grades of gunpowder have found their use in the pyrotechnic industry. The basis is potassium/sodium nitrate (needed as an oxidizer), aluminum powder (this is flammable) and sulfur, reduced to the state of powder and mixed together. Due to the large release of light during combustion and the speed of combustion, it is used in explosive elements and flash compositions (producing a flash).

Proportions (saltpeter: aluminum: sulfur):

  • bright flash - 57:28:15;
  • explosion - 50:25:25.

Gunpowder is not afraid of moisture and does not change its flowability, but it can get very dirty.


Classification of gunpowders

This is a smokeless powder that was developed in modern times. Unlike black powder, nitrocellulose has a high efficiency. And there is no smoke that the arrow can give off.

In turn, nitrocellulose powders, due to the complexity of their composition and wide application, can be divided into:

  1. pyroxylin;
  2. ballistic;
  3. cordite.

Smokeless powder is gunpowder that is used in modern types of weapons and various explosive products. It is used as a detonator.

Pyroxylin

The composition of pyroxylin powders usually includes 91-96% pyroxylin, 1.2-5% volatile substances (alcohol, ether and water), 1.0-1.5% stabilizer (diphenylamine, centralite) to increase storage stability, 2- 6% phlegmatizer to slow down the combustion of the outer layers of powder grains and 0.2-0.3% graphite as additives.

Pyroxylin powders are produced in the form of plates, ribbons, rings, tubes and grains with one or more channels; The main uses are pistols, machine guns, cannons, and mortars.

The production of such gunpowder consists of the following stages:

  • Dissolution (plasticization) of pyroxylin;
  • Composition pressing;
  • Cut from a mass with various shapes of gunpowder elements;
  • Solvent removal.

Ballistic

Ballistic powders are gunpowders of artificial origin. The largest percentage has the following components:

  • nitrocellulose;
  • non-removable plasticizer.

Due to the presence of exactly 2 components, experts call this type of gunpowder 2-basic.

If there are changes in the percentage of gunpowder plasticizer content, they are divided into:

  1. nitroglycerin;
  2. diglycol.

The structure of the composition of ballistic powders is as follows:

  • 40-60% colloxylin (nitrocellulose with a nitrogen content of less than 12.2%);
  • 30-55% nitroglycerin (nitroglycerin powders) or diethylene glycol dinitrate (diglycol powders) or a mixture thereof;

Also included are various components that have a small percentage of content, but they are extremely important:

  • dinitrotoluene– necessary to be able to control the combustion temperature;
  • stabilizers(diphenylamine, centralite);
  • Vaseline oil, camphor and other additives;
  • Fine metal can also be added to ballistic powders(an alloy of aluminum and magnesium) to increase the temperature and energy of combustion products, such gunpowder is called metallized.

Continuous technological scheme for the production of powder mass of high-energy ballistic powders


1 – agitator; 2 – mass pump; 3 – volumetric pulse dispenser; 4 – bulk components dispenser; 5 – supply container; 6 – supply tank; 7 – gear pump; 8 – APR; 9 – injector;
10 – container; 11 – passivator; 12 – water repellent; 13 – solvent; 14 – mixer; 15 – intermediate mixer; 16 – mixer of common batches

The appearance of the manufactured gunpowder is in the form of tubes, checkers, plates, rings and ribbons. Gunpowder is used for military purposes, and according to their application they are divided:

  • rocket(for charges for rocket engines and gas generators);
  • artillery(for propellant charges for artillery pieces);
  • mortar(for propellant charges for mortars).

Compared to pyroxylin powders, ballistic gunpowders are characterized by lower hygroscopicity, faster production, the ability to produce large charges (up to 0.8 meters in diameter), high mechanical strength and flexibility due to the use of a plasticizer.

The disadvantages of ballistic powders compared to pyroxylin powders include:

  1. Great danger in production due to the presence in their composition of a powerful explosive - nitroglycerin, which is very sensitive to external influences, as well as the inability to obtain charges with a diameter of more than 0.8 m, in contrast to mixed gunpowders based on synthetic polymers;
  2. Complexity of the production process ballistic powders, which involves mixing the components in warm water in order to distribute them evenly, squeezing out the water and repeated rolling on hot rollers. This removes water and plasticizes the cellulose nitrate, which takes on the appearance of a horn-like sheet. Next, the gunpowder is pressed through dies or rolled into thin sheets and cut.

Cordite

Cordite powders contain high-nitrogen pyroxylin, a removable (alcohol-ether mixture, acetone) and non-removable (nitroglycerin) plasticizer. This brings the production technology of these gunpowders closer to the production of pyroxylin gunpowder.

The advantage of cordites is greater power, but they cause increased burning of the barrels due to the higher temperature of the combustion products.


Solid rocket fuel

Synthetic polymer-based mixed propellant (solid rocket fuel) contains approximately:

  • 50-60% oxidizing agent, usually ammonium perchlorate;
  • 10-20% plasticized polymer binder;
  • 10-20% fine aluminum powder and other additives.

This direction of powder making first appeared in Germany in the 30-40s of the 20th century; after the end of the war, the active development of such fuels began in the USA, and in the early 50s - in the USSR. The main advantages over ballistic gunpowder, which attracted a lot of attention to them, were:

  • high specific thrust of rocket engines using such fuel;
  • the ability to create charges of any shape and size;
  • high deformation and mechanical properties of the compositions;
  • the ability to regulate the burning rate over a wide range.

These properties of gunpowder made it possible to create strategic missiles with a range of more than 10,000 km. Using ballistic gunpowder, S.P. Korolev, together with gunpowder makers, managed to create a rocket with a maximum range of 2,000 km.

But mixed solid fuels have significant disadvantages compared to nitrocellulose powders: the very high cost of their production, the duration of the charge production cycle (up to several months), the complexity of disposal, the release of hydrochloric acid into the atmosphere during the combustion of ammonium perchlorate.


The new gunpowder is solid rocket fuel.

Powder combustion and its regulation

Combustion in parallel layers, which does not turn into an explosion, is caused by the transfer of heat from layer to layer and is achieved by manufacturing fairly monolithic powder elements, free of cracks.

The burning rate of gunpowder depends on pressure according to a power law, increasing with increasing pressure, so you should not focus on the burning rate of gunpowder at atmospheric pressure when assessing its characteristics.

Regulating the burning rate of gunpowder is a very difficult task and is solved by using various combustion catalysts in the powder composition. Combustion in parallel layers allows you to regulate the rate of gas formation.

The gas formation of gunpowder depends on the size of the surface of the charge and its burning rate.


The surface area of ​​the powder elements is determined by their shape, geometric dimensions and can increase or decrease during the combustion process. Such combustion is called progressive or digressive, respectively.

To obtain a constant rate of gas formation or its change according to a certain law, individual sections of charges (for example, missiles) are covered with a layer of non-combustible materials (armor).

The burning rate of gunpowder depends on its composition, initial temperature and pressure.

Characteristics of gunpowder

The characteristics of gunpowder are based on parameters such as:

  • heat of combustion Q- the amount of heat released during complete combustion of 1 kilogram of gunpowder;
  • volume of gaseous products V released during the combustion of 1 kilogram of gunpowder (determined after bringing the gases to normal conditions);
  • gas temperature T, determined by combustion of gunpowder under conditions of constant volume and absence of heat losses;
  • powder density ρ;
  • gunpowder strength f- the work that could be done by 1 kilogram of powder gases, expanding when heated by T degrees at normal atmospheric pressure.

Characteristics of nitro powders

Non-military use

The ultimate main purpose of gunpowder is military purposes and use for the destruction of enemy targets. However, the composition of Sokol gunpowder allows its use for peaceful purposes, such as fireworks, construction tools (construction pistols, punches), and in the field of pyrotechnics - squibs. The characteristics of Bars gunpowder are more suitable for use in sports shooting.